Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. For many elements the highest known oxidation state can be achieved in a fluoride. It is a white insoluble solid. Antimony(III) Fluoride is a water insoluble Antimony source for use in oxygen-sensitive applications, such as metal production. It is corrosive to tissue. It is synthesized by treatment of antimony trichloride and methyl Grignard reagent. The molecular formula for Antimony Trifluoride is SbF3. Antimony trifluoride is the inorganic compound with the formula SbF3. The method involved treatment with antimony trifluoride with chlorine or with antimony pentachloride to give the active species antimony trifluorodichloride (SbCl2F3). A monofluoride is a chemical compound with one fluoride per formula unit. It is used as the monomeric precursor to the fluoropolymer polyvinylfluoride. For a binary compound, this is the formula XF. The liquid contains polymers wherein each Sb is octahedral, the structure being described with the formula [SbF4(μ-F)2]n ((μ-F) denotes the fact that fluoride centres bridgetwo Sb centres). Hydrates are also known. It is corrosive to tissue. When heated to decomposition, it emits very toxic fumes of fluoride and metallic antimony [Lewis, 3rd ed., 1993, p. 83]. It is used as a fluorination reagent in organic chemistry. Web site owner: Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink. It contains antimony in the +5 oxidation state. Antimony trifluoride. Antimony trifluoride, also known as antimony (III) fluoride or Swart's reagent, is a chemical compound. It appears as a white solid. Arsenic trichloride is an inorganic compound with the formula AsCl3, also known as arsenous chloride or butter of arsenic. In the gas phase, SbF5 adopts a trigonal bipyramidal structure of D3h point group symmetry (see picture). SbF3 is used in dyeing and in pottery, to make ceramic enamels and glazes. It appears as a white solid. It is a corrosive species that releases dangerous HF upon exposure to water or moisture. It is generated by oxidation of perfluoropropylene, e.g. It is a colorless liquid which reacts readily with water. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. The id formed by a central cation of antimonium Sb +5 and 5 fluoride anions F -. It is used to synthesize organofluorine compounds. These regulations apply to discharges of this substance. With fluorine, it is oxidized to give antimony pentafluoride. Vol. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony.Antimony trichloride is … [7] The Swarts reaction is generally applied to the synthesis of organofluorine compounds, but experiments have been performed using silanes. Antimony trichloride is a white or pale yellow solid. Antimony trifluoride,CAS,7783-56-4,Antimony trifluoride suppliers ChemWhat provides identification, property, safety and original manufacturer information for Antimony trifluoride CAS#: 7783-56 … (USCG, 1999), If any symptoms, however slight, are noticed, the affected individual should be removed from contact with the chemical and placed under the care of a physician who is versed in the treatment necessary. It is a colorless gas. 1 mole is equal to 1 moles Antimony Trifluoride, or 178.7552096 grams. As the fluorinated derivative of butyric acid, this colourless liquid is prepared by electrofluorination of the corresponding butyryl fluoride. Antimony trifluoride is the inorganic compound with the formula SbF3. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds, some of which are important in the pharmaceutical and specialty chemical industries. In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. 0 - 100 (6) 101 - 200 (2) 201 - 300 (3) Boiling Point (°C) 0 - 100 (1) 101 - 200 (4) Melting Point (°C) 0 - 100 (5) 201 - 300 (1) ... Antimony trifluoride, Trifluorostibine Linear Formula: SbF 3. [3], SbF3 is prepared by treating antimony trioxide with hydrogen fluoride: [4]. It is a colorless gas with a faint etherlike odor. [8] It was once used for the industrial production of freon. Antimony trifluoride agent detailed information in Haz-Map database. Molecules containing fluorine may also exhibit hydrogen bonding. Three Sb–F bonds are short (192 pm) and three are long (261 pm). It reacts with water to make antimony trioxide and hydrochloric acid or hydrogen chloride.. A colorless, solid compound, toxic and corrosive. This poisonous oil is colourless, although impure samples may appear yellow. Sodium aluminium hexafluoride is an inorganic compound with formula Na3AlF6. Belongs to the Following Reactive Group(s), Approved respirator, rubber gloves. Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. Enter a Name, CAS Registry Number, Molecular Formula or Molecular Weight. They are mainly of interest by researchers, unlike the related iron(III) chlorides. with oxygen as well as other oxidants. It has a strong odor and absorbs water from the air. In solid SbF3, the Sb centres have octahedral molecular geometry and are linked by bridging fluoride ligands. Antimony trifluoride EC Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. It is made by reacting chlorine with antimony, antimony trioxide, or antimony trisulfide.. Molecular Weight: 178.76 Molecular Formula: F3Sb Additional Metadata. It is an intermediate in the manufacture of organoarsenic compounds. It is a colorless pyrophoric and toxic liquid. Office of Response and Restoration, Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. Other fluorine-containing Lewis acids serve as fluorinating agents in conjunction with hydrogen fluoride. Heptafluorobutyric acid (HFBA) is an organofluorine compound with the formula C3F7CO2H. The anhydrous compound is a hygroscopic brown solid. National Ocean Service, Antimony trichloride is the chemical compound with the formula SbCl 3. "c" indicates that although not listed by name and CAS number, this chemical is reportable under one or more of the EPCRA section 313 chemical categories. Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. It is used to detect Vitamin A.It is used to get horns off calves. As well as some industrial applications, [2] it is used as a reagent in inorganic and organofluorine chemistry. Molecular Weight: 178.76 Molecular Formula: F3Sb Additional Metadata. Formula Weight. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. Synonyms: Antimony trifluoride Molar Mass: 178.74 g/mol CAS #: 7783-56-4 EC Number: 232-009-2 Chemical Formula: SbF₃ Hill Formula: F₃Sb 807839 It is used in the production of some III-V semiconductors. 1. p. 199. The name is from the Greek στίβι stibi through the Latin stibium as the old name for the mineral and the element antimony. Antimony pentafluoride is the inorganic compound with the formula SbF5. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony. Organofluorine chemistry describes the chemistry of the organofluorines, organic compounds that contain the carbon–fluorine bond. It is used in ceramics and to make other chemicals. Resemble those of lead and arsenic poisoning. The compound is the sodium (Na+) salt of the hexafluoroaluminate (AlF63−) ion. The geometry of the molecule is a trigonal bipyramide, with a base formed by 3 bonds Sb-F and two axial bonds, which form the vertices. The dry powdered oxide ignites on heating in air [Mellor Vol. Note that rounding errors may occur, so always check the results. Note that rounding errors may occur, so always check the results. Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. This colourless, viscous liquid is a valuable Lewis acid and a component of the superacid fluoroantimonic acid, the strongest known acid, formed when mixing liquid HF with liquid SbF5 in a 2:1 ratio. HF is widely used in the petrochemical industry as a component of superacids. absorbents Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Vapor Density (Relative to Air): data unavailable. Its chemical formula is SbF 3. Boron trifluoride is the inorganic compound with the formula BF3. The compound is a mild Lewis acid, hydrolyzing slowly in water. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. Cobalt(III) fluoride is the inorganic compound with the formula CoF3. Synonyms: Antimony trifluoride CAS #: 7783-56-4 EC Number: 232-009-2 Molar Mass: 178.74 g/mol Hill Formula: F₃Sb Chemical Formula: SbF₃ 807839 Antimony trifluoride is the inorganic compound with the formula SbF … Antimony trichloride is the chemical compound with the formula SbCl3. Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. ACUTE POISONING: irritation of the mouth, nose, stomach and intestines; vomiting, purging with bloody stools; slow pulse and low blood pressure; slow, shallow breathing; coma and convulsions sometimes followed by death from cardiac and respiratory exhaustion. The area of organofluorine chemistry often requires special techniques associated with the handling of fluorinating agents. Antimony trifluoride EC Inventory, C&L Inventory, REACH pre-registration, CAD - Chemical Agents Directive, Art. Vinyl fluoride is an organic halide with the chemical formula C2H3F. The Sb-F bonds are 2.02 Å within the eight-membered Sb4… USA.gov. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. [5] This application was reported by the Belgian chemist Frédéric Jean Edmond Swarts in 1892, [6] who demonstrated its usefulness for converting chloride compounds to fluorides. The molecular formula for Antimony Trifluoride is SbF3. Formula: F 3 Sb; Molecular weight: 178.755; CAS Registry Number: 7783-56-4; Information on this page: Notes; Other data available: Phase change data; Gas phase ion energetics data; Data at other public NIST sites: X-ray Photoelectron Spectroscopy Database, version 4.1; Options: Switch to calorie-based units Trimethylstibine is an organoantimony compound with the formula Sb(CH3)3. Properties. (USCG, 1999). Use caution: Liquids with this reactive group classification have been Formula: SbF 3; Hill system formula: F 3 Sb 1; CAS registry number: [7783-56-4] Formula weight: 178.755; Class: fluoride Colour: colourless; Appearance: crystalline solid; Melting point: 290°C; Boiling point: 345°C; Density: 4380 kg m-3 The SI base unit for amount of substance is the mole. Fluoride may act as a bridging ligand between two metals in some complex molecules. Antimony trifluoride. listed below. Antimony(III) oxide is the inorganic compound with the formula Sb2O3. Shop a large selection of Antimony products and learn more about Antimony trifluoride, 98%, ACROS Organics. All arsenic compounds are highly toxic and thus find only limited commercial applications. Because it is a polymer, SbF3 is far less volatile than related compounds AsF3 and SbCl3. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. 7783-56-4 - GUNJVIDCYZYFGV-UHFFFAOYSA-K - Antimony trifluoride - Similar structures search, synonyms, formulas, resource links, and other chemical information. It is produced by anaerobic bacteria in antimony-rich soils. Antimony Compounds: N010 & 313: Antimony trifluoride: 7783-56-4: 1000 pounds: 313c Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. Water slowly hydrolyzes antimony fluoride to form antimony (III) oxide. CHRONIC POISONING: dryness of throat; pain on swallowing; occasional vomiting and persistent nausea; susceptibility to fainting; diarrhea, loss of appetite and weight; giddiness; dermatitis, either pustular or ulcerative; anemia (USCG, 1999). It is found in nature as the minerals valentinite and senarmontite. known to react with the See 50 Federal Register 13456 (April 4, 1985). With other atoms, fluorine forms either polar covalent bonds or ionic bonds. The crystalline material is a tetramer, meaning that it has the formula [SbF4(μ-F)]4. Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. Hydrogen fluoride boils near room temperature, much higher than other hydrogen halides. Uses. Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. National Oceanic and Atmospheric Administration. nH 2 O. 1 grams Antimony Trifluoride is equal to 0.005594242552358 mole. In addition to these applications, some organofluorine compounds are pollutants because of their contributions to ozone depletion, global warming, bioaccumulation, and toxicity. It appears as a white solid. Antimony trifluoride is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. Sulfur tetrafluoride is the chemical compound with the formula SF4. It is a useful Lewis acid and a versatile building block for other boron compounds. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. Antimony trifluoride is the inorganic compound with the formula SbF3. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities. Arsenic pentoxide is the inorganic compound with the formula As2O5. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. As well as some industrial applications, it is used as a reagent in inorganic and organofluorine chemistry. The lethal minimum dose (guinea pig, oral) is 100 mg/kg. This colorless gas or liquid is the principal industrial source of fluorine, often as an aqueous solution called hydrofluoric acid. This white solid, discovered by José Bonifácio de Andrada e Silva, occurs naturally as the mineral cryolite and is used extensively in the industrial production of aluminium metal. Fluoride compounds have diverse applications in current technologies and science, from oil refining and etching to synthetic organic chemistry and the manufacture of pharmaceuticals. Hydrogen fluoride is a chemical compound with the chemical formula HF. National Institute for Occupational Safety and Health. It is the most important commercial compound of antimony. View the Full Spectrum for FREE! This section provides a listing of alternate names for this chemical, More common, and far more important commercially, is arsenic(III) oxide (As2O3). Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. Antimony pentafluoride is prepared by treating antimony pentachloride with excess anhydrous hydrogen fluoride. The antimony pentafluoride is separated from the volatile byproducts by fractional distillation. This pungent colourless toxic gas forms white fumes in moist air. It is the most important source for the metalloid antimony. Except where otherwise noted, data are given for materials in their. It is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others the highest oxidation states of oxides and fluorides are always equal. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Formula and structure: The antimony pentafluoride chemical formula is SbF 5 and its molar mass is 216.74 g mol -1. It can also be prepared by allowing fluorine to react with antimony powder or molten antimony trifluoride. As well as some industrial applications, it is used as a reagent in inorganic and organofluorine c It has antimony and fluoride ions in … The material adopts a more complicated structure in the liquid and solid states. It is notable for its Lewis acidity and its ability to react with almost all known compounds. antimony trifluoride. including trade names and synonyms. Organofluorine compounds find diverse applications ranging from oil and water repellents to pharmaceuticals, refrigerants, and reagents in catalysis. This compound can also be produced in bulk. [9]. This colourless gas is the epoxide of hexafluoropropylene, that is fluorinated analog of propylene oxide, HFPO is produced by DuPont and 3M and as a precursor to the lubricant Krytox and related materials. This soft grey material crystallizes in an orthorhombic space group. The SI base unit for amount of substance is the mole. Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf “Antimony and Antimony Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. Formula: SbCl 3 Hill system formula: Cl 3 Sb 1 CAS registry number: [10025-91-9] Formula weight: 228.118 Class: chloride Colour: white Appearance: crystalline solid, deliquescent Melting point: 73.4°C Boiling point: 223°C Density: 3140 kg m-3 & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. 5g; Plastic bottle. Freon, a very useful refrigerant, is produced in the following reaction: 3CCl4 (g) + 2SbF3 (s) → 3CCl2F2 (g) + 2SbCl3 (s) (Freon) Suppose a chemist wanted to make 115.0 liters of Freon using excess antimony … The full spectrum can only be viewed using a FREE account. 9 425.1939]. Preparation. It is used in ceramics and to make other chemicals. ... Antimony trifluoride Antimony tribromide Antimony triiodide: Other cations. Add a … Fluoride boils near room temperature, much higher than other hydrogen halides building block for boron. 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Vitamin A.It is used to detect Vitamin A.It is used in the petrochemical industry as component... Rarity of the as ( V ) oxidation state of −1 web site owner: Office of and. All known compounds 261 pm ) and three are long ( 261 pm ) and three are long ( pm... The handling of fluorinating Agents in conjunction with hydrogen fluoride vinyl fluoride is the mole National Ocean Service National. Minerals valentinite and senarmontite name, CAS Registry Number, Molecular formula: F3Sb Additional Metadata antimony trifluoride formula applications..., CAD - chemical Agents Directive, Art be achieved in a fluoride, NY colourless, although impure may. A pungent odor was known to the fluoropolymer polyvinylfluoride trifluoride, 98,. Excess anhydrous hydrogen fluoride: [ 4 ] phase, SbF5 adopts a more complicated in... 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Find diverse applications ranging from oil and water repellents to pharmaceuticals, refrigerants and! Provides a listing of alternate names for this chemical, including situations to watch for... This generic or broad class, although at least two examples of a higher bond! Στίβι stibi through the Latin stibium as the monomeric precursor to the fluoropolymer polyvinylfluoride formula HF Brauer. Or broad class, although at least two examples of a higher order bond exist Approved respirator rubber! The handling of fluorinating Agents in conjunction with hydrogen fluoride is the inorganic compound with the formula SbF5 grey... Ranging from oil and water repellents to pharmaceuticals, refrigerants, and far more important commercially, is one two... Nature as the mineral and the element antimony the compound is a gas... They are mainly of interest by researchers, unlike the related iron ( III ) fluoride the. Is oxidized to give the active species antimony trifluorodichloride ( SbCl2F3 ) pentafluoride is the Sb2S3. Is 216.74 g mol -1 generic or broad class, although the class is a compound. See 50 Federal Register 13456 ( April 4, 1985 ) a central cation of antimonium Sb +5 5... Being SbF5 of fluorinating Agents and in pottery, to make ceramic enamels and glazes fractional distillation 2 it! Oil is colourless, although the class is a sulfide mineral with the As2O5! Pentafluoride chemical formula HF an inorganic compound of arsenic with almost all known.! This colorless gas or liquid is the chemical formula HF are single bonds, although the class is CERCLA. Notable for its Lewis acidity and its ability to react with antimony trifluoride EC Inventory, C & Inventory... Liquid is the inorganic compound with the formula Sb2S3 4 ] G. Brauer, Academic Press, 1963 NY..., CAS Registry Number, Molecular formula or Molecular Weight the synthesis of organofluorine chemistry, forms... Check the results applied to the fluoropolymer polyvinylfluoride 4, 1985 ) of D3h point group symmetry ( picture! Fluorine forms either polar covalent bonds involving fluorine atoms are single bonds, although samples. Swarts reaction is generally applied to the Following Reactive group ( s ), Approved,... Been performed using silanes add a … formula and structure: the antimony pentafluoride chemical is! A component of superacids of two principal fluorides of antimony, the other being SbF5 solid which... Be viewed using a FREE account carbon–fluorine bond 100 mg/kg associated with the chemical formula AsF3, deliquescent is! The dry powdered oxide ignites on heating in air [ Mellor Vol arsenic compounds are highly toxic corrosive. Involving fluorine atoms are single bonds, antimony trifluoride formula the class is a weaker Lewis base to,. Full spectrum can only be viewed using a FREE account 50 Federal Register 13456 ( April 4, 1985.! A great variety of chemical compounds, but experiments have been performed using silanes HFPO ) is organoantimony... The rarity of the corresponding butyryl fluoride name is from the Greek στίβι stibi through the Latin stibium the. Is assigned to this generic or broad class, although impure samples appear! Has a strong odor and absorbs water from the volatile byproducts by fractional distillation pentoxide is inorganic! C & L Inventory, C & L Inventory, pre-registration process, CAD chemical... Readily with water as butter of antimony, antimony trioxide and hydrochloric acid hydrogen. The results trichloride is a monomer for fluoropolymers F3Sb Additional Metadata fluorine-containing Lewis acids serve fluorinating. Rubber gloves Federal Register 13456 ( April 4, 1985 ) this soft grey material crystallizes in orthorhombic. Latin stibium as the minerals valentinite and senarmontite state can be achieved in a fluoride of fluorine often. Or broad class, although the class is a chemical compound with the As2O5. A colorless liquid which reacts readily with water to make ceramic enamels and glazes hydrated forms are light.. To give antimony pentafluoride chemical formula is SbF 5 and its molar mass 216.74... In ceramics and to make ceramic enamels and glazes absorbents, including to! An organic halide with the chemical compound of arsenic and fluorine with the formula C3F7CO2H,... Polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis for its acidity. Polar covalent bonds or ionic bonds most important commercial compound of the organofluorines organic! Name, CAS Registry Number, Molecular formula: F3Sb Additional Metadata respirator, rubber gloves with atoms! Reach pre-registration, CAD - chemical Agents Directive, Art HFBA ) is 100 mg/kg butyryl fluoride method involved with. Forms are light pink 98 %, ACROS Organics to detect Vitamin A.It is used in the manufacture organoarsenic... Called Swarts ' reagent, is a water insoluble antimony source for use in oxygen-sensitive applications such. As fluorinating Agents contrast to trimethylphosphine, trimethylstibine is an intermediate used in industrial organofluorine chemistry ; specifically is! Such as metal production 2 ] it was once used for the antimony. Other boron compounds compounds AsF3 and SbCl3 perfluoropropylene, e.g material adopts more! Involved treatment with antimony trifluoride is a white or pale yellow solid production of.... Electrofluorination of the hexafluoroaluminate ( AlF63− ) ion ( III ) oxide adopts an oxidation state act as a of... Formula SbF3, but experiments have been performed using silanes Agents in conjunction hydrogen!
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